Tetraetunilmetana

Tetraetunilmetana
Nama
	Nama IUPAC (preferensi) 3,3-dietunilpenta-1,4-diuna
Penanda
Model 3D (JSmol)	Gambar interaktif;
3DMet	{{{3DMet}}}
Nomor EC
PubChem CID	14934811;
Nomor RTECS	{{{value}}}
	InChI InChI=1S/C9H4/c1-5-9(6-2,7-3)8-4/h1-4H Key: JVMGUYOVBKXTJL-UHFFFAOYSA-N;
	SMILES C#CC(C#C)(C#C)C#C;
Sifat
Rumus kimia	C9H4
Massa molar	112,13 g·mol−1
	Kecuali dinyatakan lain, data di atas berlaku pada suhu dan tekanan standar (25 °C [77 °F], 100 kPa).
	Referensi

Tetraetunilmetana adalah sebuah senyawa organik dengan rumus C₉H₄, terdiri dari empat gugus etunil yang terikat pada atom karbon pusat. Ia adalah senyawa alkuna, dan salah satu hidrokarbon paling kompak. Ia telah disintesis untuk aplikasi potensial dalam sintesis bentuk karbon polimer seperti fulerena dan intan sintetis.^[1]^[2]^[3]^[4]^[5]^[6]

Lihat pula[sunting | sunting sumber]

Referensi[sunting | sunting sumber]

^ Feldman KS, Kraebel CM, Parvez M (Mei 1993). "Tetraethynylmethane". Journal of the American Chemical Society. 115 (9): 3846–3847. doi:10.1021/ja00062a089.
^ Feldman KS, Weinreb CK, Youngs WJ, Bradshaw JD (Oktober 1994). "Preparation and some subsequent transformations of tetraethynylmethane". Journal of the American Chemical Society. 116 (20): 9019–9026. doi:10.1021/ja00099a020.
^ Feldman KS, Mareska DA, Weinreb CK, Chasmawala M (Januari 1996). "Preliminary studies towards crosslinking polymerizations with tetraethynylmethane and its derivatives: evidence for unusually facile alkyne hydration". Chemical Communications (7): 865–866. doi:10.1039/CC9960000865.
^ Amemiya R, et al. One-Step Synthesis of Triethynylvinylmethanes and Tetraethynylmethanes by GaCl 3 -Promoted Diethynylation of 1,4-Enynes and 1,4-Diynes. Journal of the American Chemical Society 2005; 127(23):8252-3. DOI:10.1021/ja051416l
^ Zhao Z, et al. A 3D Organically Synthesized Porous Carbon Material for Lithium-Ion Batteries. Angewandte Chemie 2018; 57(37): 11952-11956. DOI:10.1002/anie.201805924
^ Kilde MD, Murray AH, Andersen CL, et al. Synthesis of radiaannulene oligomers to model the elusive carbon allotrope 6,6,12-graphyne. Nat Commun 2019;10:3714. DOI:10.1038/s41467-019-11700-0

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[1] Feldman KS, Kraebel CM, Parvez M (Mei 1993). "Tetraethynylmethane". Journal of the American Chemical Society. 115 (9): 3846–3847. doi:10.1021/ja00062a089.

[2] Feldman KS, Weinreb CK, Youngs WJ, Bradshaw JD (Oktober 1994). "Preparation and some subsequent transformations of tetraethynylmethane". Journal of the American Chemical Society. 116 (20): 9019–9026. doi:10.1021/ja00099a020.

[3] Feldman KS, Mareska DA, Weinreb CK, Chasmawala M (Januari 1996). "Preliminary studies towards crosslinking polymerizations with tetraethynylmethane and its derivatives: evidence for unusually facile alkyne hydration". Chemical Communications (7): 865–866. doi:10.1039/CC9960000865.

[4] Amemiya R, et al. One-Step Synthesis of Triethynylvinylmethanes and Tetraethynylmethanes by GaCl 3 -Promoted Diethynylation of 1,4-Enynes and 1,4-Diynes. Journal of the American Chemical Society 2005; 127(23):8252-3. DOI:10.1021/ja051416l

[5] Zhao Z, et al. A 3D Organically Synthesized Porous Carbon Material for Lithium-Ion Batteries. Angewandte Chemie 2018; 57(37): 11952-11956. DOI:10.1002/anie.201805924

[6] Kilde MD, Murray AH, Andersen CL, et al. Synthesis of radiaannulene oligomers to model the elusive carbon allotrope 6,6,12-graphyne. Nat Commun 2019;10:3714. DOI:10.1038/s41467-019-11700-0

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